"Running the heater hard" will actually help keep the engine temps under control. Using the heater doesn't add heat to the engine.
Pressurized systems will allow the boiling point to be raised above the atmospheric norm. For water, that's 212F / 100C at sea level, and lower as you go up in altitude. I don't have a reference to show the higher boiling point for different pressures, but so long as your system doesn't exceed that point, you'll still be flowing liquid. When it vaporizes at the boiling point, it takes up a lot more room and could cause the overflow to bleed of excess coolant to make room for the vapors.